Taking the enterprise and the union as organizational targets, and dual commitment as the mediate variable, this paper explores the impact of employees' organizational status perception on their turnover intention in the context of Chinese non-state enterprises. 433 employees of non-state enterprises with effective unions in Jiangsu Province were tested through a questionnaire survey. The findings indicate that employees' status perception in the enterprise is negatively correlated with their enterprise turnover intention; employees' status perception in the union is negatively correlated with their union turnover intention; negative correlations were found between dual commitment and enterprise turnover intention, and between dual commitment and union turnover intention; dual commitment partly mediates the relationship between the status perception in the enterprise and the enterprise turnover intention, as well as the relationship between the status perception in the union and the union turnover intention. These findings can not only guide the construction of harmonious labor relations climate in Chinese non-state enterprises in the phase of social-economic transition, but also help to build effective relationships between enterprises and unions in their management practices.