He-Xie Management Theory is analyzed from the perspective of Person-Environment Fit in this study. Conceptualization of Organizational He-Xie Management is discussed, and two practical model of He-Xie Management are reviewed. To meet the challenge to single organizational view, the Employees-Organization Complex view of Person-Environment Fit is introduced into the study of He-Xie Management Theory, about which two operational models are formulated. Based on a series of hypotheses, a new operational model and a new conceptual Model of Organizational He-Xie Management are developed, which build a clear systemic analysis framework in practical and empirical study. The paper also explains the theory of Person-Environment Fit in Chinese context.