From a macro perspective, this paper sets up competitive relationship network models by using complex network and analysis properties of the competitive relationship complex network for China's logistics industry. The results show that competitive relationship networks exhibits the characteristics of small-world and scale-free. Finally, by giving an economics explanation for properties of the competitive relationship networks, this paper points out that complex networks  provide a new tool and means to analyze enterprises' competitive relationship and competitive behaviors and for the governments to establish competitive industry policies.