Through the survey on 500 employees in a large-scale enterprise, this study investigated the relationship between leadership behavior and leadership performance with leading the leadership value as a moderator variable, which is divided into four dimension as self-transcendence, self-enhancement, conservation and openness to change. The research results revealed that when the leadership value tends to be the self-transcendence dimension, the leadership behavior produces the highest leadership performance; When the leadership value tends to be the self-enhancement dimension, the displaying abilities-oriented leadership behavior has the most significant influence on leadership performance; When the leadership value tends to be conservation dimension, the avoiding failure-oriented leadership behavior has the most significant influence on leadership performance; When the leadership value tends to be openness to change dimension, the developing employees-oriented leadership behavior has the most significant influence on leadership performance. Finally, this study points out the importance of leadership values in selecting and hiring talents.